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1 kcalmol (226 kJmol) CH3CH2CH2CH2CH3 CH3CH2CH2CH2CH3 CH3CH2CH2CH2CH3 Ho Ho Ho 3-D Molecules: 2,3-Pentadiene; 1,4-Pentadiene; 1,3-Pentadiene 2,3-pentadiene a cumulated diene CH2 CHCH2CH CH2 1,4-pentadiene Pt 2 H Pt 2 H2 an isolated diene CH CHCH CHCH 232 1,3-pentadiene a conjugated diene relative stabilities of dienes most conjugated diene isolated diene stable cumulated diene least stable single bond formed by sp2sp2 overlap CH2 CH CH CH2 1,3-butadiene single bonds formed by sp3sp2 overlap CH2 CH CH2 CH CH2 1,4-pentadiene Tutorial: Orbitals used to form carboncarbon single bonds From the relative -¢H° values for the three pentadienes, we can conclude that con- jugated dienes are more stable than isolated dienes, which are more stable than cumu- lated dienes.
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